The initiative will provide a copy of the collection to all primary schools in England.
Boris Johnson says he hopes to reopen England's schools from March 8, as he confirms hotel quarantine plan.
Schools could reopen from 8 March if the UK meets vaccination targets, the prime minister says.
The measures will apply to British residents returning to England from areas including southern Africa.
Boris Johnson says he takes "full responsibility", saying: "We truly did everything we could."
Travellers share their experiences of isolating in hotels, as UK ministers prepare a similar scheme.
Nadhim Zahawi says supply is tight, but he expects the UK to meet its February target of 15 million doses.